Brass that has been fired in that specific rifle and then correctly resized always will provide more reliable ignition along with better accuracy.
Correctly resized means using head space gauges to make sure the shoulder is set back 0.002” - 0.003”, and absolutely no more than 0.005”.
If it is a belted mag, some dies will not do a good job of sizing the area in front of the belt and a bulge develops. There are dies made specifically for resizing that area in front of the belt, if needed.
For a final quality control check, point the muzzle toward the ground and drop a round into the chamber. It should drop all the way in without having to use the bolt to push it in. This check also can reveal a need for cleaning in that area or burrs.
The problem with some new brass or an incorrectly adjusted sizing die is there is too much room between the shoulder and the chamber wall, which is what is meant by excessive headspace. When the firing pin hits the primer, the firing pin pushes the cartridge forward until it hits the chamber wall and only then does the firing pin begin to indent the primer. Excessive headspace causes a weak indention of the primer and potential ignition problems.
On rimmed cartridges, the rim controls headspace.
On belted mags, originally the belt was created to act like the rim on a rimmed cartridge and provide the stop just as the rim does on a rimmed cartridge. SAAMI and CIP specs for many/most belted cartridges still use the belts for headspace measurements. On .300 Win Mag as just one common example, new brass will have 0.010” of space forward of the shoulder, but it still fires fine because the belt keeps the cartridge from moving forward - that is the reason for the belt. The belt really was needed back when the .300 H&H was created because of its long gently sloping shoulder to assure reliable ignition.
Modern cartridge designs like the .300 Win Mag with sharper shoulders, but which still have belts, really benefit from using fired brass resized to headspace off of the shoulder rather than the belt.